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2.1 Atoms and Molecules

2.1 Atoms and Molecules
2.1  ·  Atoms & Molecules

Everything is built
from atoms
& molecules.

Matter — everything around us — is made of very small particles. Understanding how these particles are structured and combine explains how substances form and react.

Definition Dalton’s postulates Modern position Limitations
01

Atoms & Molecules — the basics

Atom

The smallest unit

The smallest fundamental unit of an element that still shows the properties of that element. Atoms are the smallest units of an element that take part in chemical reactions.

Most atoms don’t exist freely in nature — noble gases are the exception.

Cl  → one chlorine atom
Molecule

Exists independently

The smallest particle of an element or compound that exists independently, carrying all the properties of that element or compound.

CO₂  → compound   |   Cl₂  → element

🧱  Atoms are the building blocks. Molecules are groups of atoms joined together.

Homoatomic molecules — same element

Molecules made of atoms of the same element are classified by how many atoms they contain.

TypeAtomsExamples
Monoatomic1He, Ne, Ar (noble gases)
Diatomic2H₂, O₂, N₂, Cl₂, F₂, Br₂, I₂
Triatomic3O₃ (ozone)
Tetra-atomic4P₄ (phosphorus)
Octa-atomic8S₈ (sulfur)

mono = 1  ·  di = 2  ·  tri = 3  ·  tetra = 4  ·  octa = 8

Heteroatomic molecules — different elements

H₂OWater — 2 hydrogen + 1 oxygen
CO₂Carbon dioxide — 1 carbon + 2 oxygen
H₂SO₄Sulfuric acid — 2 H + 1 S + 4 O

⭐ Remember

Molecule of an element — atoms of the same element. Example: O₂

Molecule of a compound — atoms of different elements. Example: H₂O

02

Dalton’s Atomic Theory

Long before microscopes existed, the Greek thinker Democritus proposed that matter is made of very small, indivisible parts he called “atoms” — but he had no scientific proof. It wasn’t until 1808, when John Dalton gave the first scientific atomic theory, grounded in the experimental evidence of his time.

↗ How did the ancient Greeks predict the atom?

01

All matter is made up of very small particles called atoms. These particles cannot be broken down further — they are indivisible.

02

Atoms cannot be created, destroyed, or changed into atoms of a different element.

03

All atoms of the same element are alike — they share the same size, mass, and properties.

04

Atoms of different elements differ in shape, size, and mass.

05

Atoms join in simple whole-number ratios to form “compound atoms” — what we now call molecules.

Modern experiments show these postulates aren’t precisely true in their original form — but modern chemistry was built on this very foundation.

03

Limitations & the Modern View

Dalton’s theory was a landmark beginning — but later discoveries showed some of his ideas needed correction.

01 Atomic structure

An atom can be subdivided — it’s a complex structure of electrons, protons, and neutrons.

02 Isotopes

Atoms of the same element may not be identical. Isotopes share the same atomic number but have different atomic masses.

Chlorine → Cl-35 and Cl-37
03 Combining ratios

Dalton proposed simple whole-number ratios. Modern chemistry shows ratios can be far more complex.

Soap C₁₈H₃₅O₂Na → 18∶35∶2∶1   |   Cane sugar C₁₂H₂₂O₁₁ → 1.09∶2∶1
04 Molecules, not “compound atoms”

Molecules — not “compound atoms” — are the smallest particles with independent existence. A molecule of an element has identical atoms; a molecule of a compound has dissimilar atoms.

O₂ → same atoms   |   CaCO₃ → different atoms
05 Radioactive change

Atoms can be altered. Some radioactive elements change into atoms of another element by emitting radiation.

₉₂U²³⁸ → ₉₀Th²³⁴ + ₂He⁴

Summary

Dalton’s ideaModern science
Atom cannot be dividedAtom contains smaller particles
Atoms of the same element are alikeIsotopes have different masses
Atoms combine in simple ratiosSome ratios are larger / less familiar
“Compound atom”Molecule
Atoms cannot change into another elementNuclear reactions can change elements
04

Important Questions

Write down the postulates of Dalton’s atomic theory.
Discuss Dalton’s atomic theory in the light of modern knowledge. [4]
State the modifications made to Dalton’s atomic theory. [4]
Explain the modern position of Dalton’s atomic theory.
05

Test Yourself 🧪

Try this quick quiz to check your understanding of atoms and molecules.

Welcome to your 2.1 Dalton's atomic theory - quiz

06

Key Vocabulary Helper महत्त्वपूर्ण शब्दकोश

Englishनेपाली अर्थSimple explanation
AtomपरमाणुSmallest unit of an element
MoleculeअणुSmallest particle that can exist independently
Elementतत्त्वA pure substance made of only ONE kind of atom (e.g., pure gold, oxygen)
CompoundयौगिकA substance made of TWO or more different atoms (e.g., water: H₂O)
Postulateअवधारणा / बुँदाMain statement or rule proposed in a scientific theory
Limitationसीमा / कमी-कमजोरीPoints where an old theory fails or needs correction

📥 Download PDF 2.1 Atoms & Molecules- Notes

📥 Download PDF 2.1 Atoms & Molecules- MCQs

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